A novel three-dimensional inorganic framework: hydrothermal synthesis and crystal structure of CuMo3O10 center dot H2O

作者：Tian CG; Wang EB^*; Li YG; Xu L; Hu CW; Peng J

来源：Journal of Solid State Chemistry, 2004, 177(3): 839-843.

DOI：10.1016/j.jssc.2003.09.017

• crystal structure
• bimetallic open framework
• isopolyoxomolybdate chains
• hydrothemial synthesis

A novel three-dimensional inorganic bimetallic compound Cu[Mo3O10].H2O 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compound 1 crystallizes in the orthorhombic system, space group pnma a = 8.6085(17) Angstrom, b = 7.5822(15) Angstrom, c = 13.690(3) Angstrom, V = 893.6(3) Angstrom(3) Z = 4. lambda(MoKalpha) = 0.71073 Angstrom (R(F) = 0.0357 for 1101 reflections). The structure of compound 1 is based on [{Mo3O10}(2-)](infinity) isopolyoxomolybdate chains bonded together with CuO4 tetrahedra into a three-dimensional inorganic open framework. Three types of Mo-Cu layers and one-dimensional tunnels Lire observed in the title compound.

• 出版日期2004-3
• 单位东北师范大学