450 degrees C and 600 degrees C Isothermal Sections of the Zn-Cr-Si Ternary Phase Diagram

作者：Yan, Yangtian; Su, Xuping^*; Liu, Ya; Ding, Yuwen

来源：Journal of Phase Equilibria and Diffusion, 2018, 39(2): 166-175.

DOI：10.1007/s11669-018-0619-2

• Zn-Cr-Si system
• isothermal section
• phase equilibria
• thermodynamics

The 450 and 600 A degrees C isothermal sections of the Zn-Cr-Si system were experimentally constructed using scanning electron microscopy equipped with energy dispersive x-ray spectrometry, and x-ray diffraction. Six three-phase regions in the 450 A degrees C section and five three-phase regions in the 600 A degrees C section were identified experimentally. No ternary compound was found. Si has low solubility in CrZn17. The Zn solubility in CrSi2, Cr5Si3, and Cr3Si are all less than 2.2 at.%. The CrSi phase cannot be in equilibrium with the eta-Zn phase. Thermodynamic extrapolation of the Zn-Cr-Si system was carried out and showed good agreement with experimentally determined phase relationships.

• 出版日期2018-4
• 单位常州大学