Dihydroxy capped triblock DTC and CL oligomers prepared by an alkyl glycol/yttrium phenolate system

作者：Chen W; Ling J; Shen ZQ^*

来源：Chinese Chemical Letters, 2005, 16(2): 282-284.

• rare earth catalyst
• block oligomer
• 2,2-dimethyltrimethylene carbonate
• epsilon-caprolactone

Dihydroxy capped triblock oligomers of 2, 2-dimethyltrimethylene carbonate (DTC) and c-caprolactone (CL) with number-average molecular weight from 3,000 to 12,000 g/mol have been synthesized by alkyl glycol initiator in the presence of yttrium tri(2, 6-di-tert-butyl-4-methylphenolate)s (Y(OAr)(3)) catalyst. They are expected to be used as macroinitiators for the design of new polymeric materials.

• 出版日期2005-2
• 单位浙江大学