Alkoxido-bridged binuclear copper(II) complexes derived from aminoalcohols - useful building blocks in designing coordination polymers with a rich structural variety

作者：Mocanu Teodora; Tudor Violeta; Andruh Marius

来源：CrystEngComm, 2017, 19(26): 3538-3552.

DOI：10.1039/c7ce00798a

The reactions of copper(ii) salts with aminoalcohols frequently afford alkoxido-bridged dimes. Neutral (e.g. bis(4-pyridyl) derivatives) or anionic divergent ligands (e.g. polycarboxylate anions, polycyanido-metallates) are employed as spacers. In this paper, a rich variety of structures are reviewed, emphasizing the role played by the denticity of the aminoalcohols and of the linkers, as well as by the accompanying anions, in the network topology. The involvement of coordinative and non-covalent bonds (pi-pi stacking, argentophilic/aurophilic, pi center dot center dot center dot Hg interactions, hydrogen bonds) in sustaining the solid-state architectures is also discussed.

• 出版日期2017-7-4