科研之友
微信
新浪微博
Facebook
分享链接
摘要
Anew Al3+-specific fluorescent probe NQ was designed and synthesized from 2-hydroxy-1-naphthaldehyde and 2-aminoquinoline. Upon the addition of Al3+, the fluorescent intensity of NQ was significantly enhanced compared with other examined metal ions in aqueous solution. The result of a Job's plot indicated the formation of a 1:1 complex between the probe and Al3+, and the possible binding mode of the system between NQ and Al3+ was clarified by IR analysis and H-1 NMR titration. Moreover, other metal ions examined had little effect on the detection of Al3+. The detection limit of NQ for Al3+ detection was 1.98 mu M, which is lower than the level (7.4 mu M) in drinking water defined by the World Health Organization. In addition, the fluorescent probe NQ could be recyclable simply through treatment with a proper reagent such as F-, and could also be used for the detection of Al3+ in real samples.
- 出版日期2017-6
- 单位南昌大学
