UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(I) pincer complex

作者:Hauser Simone A; Emerson King Jack; Habershon Scott; Chaplin Adrian B*
来源:Chemical communications, 2017, 53(26): 3634-3636.
DOI:10.1039/c6cc09807j

摘要

Iridium(I) carbonyl complex [Ir(2,6-((PBu2CH2)-Bu-t)(2)C6H3)(CO)] undergoes reversible C-H bond activation of benzene and a series of fluorobenzenes on UV irradiation. Exclusive ortho-selectivity is observed in reactions of fluorobenzene and 1,2-difluorobenzene.

  • 出版日期2017-4-4