Selective Growth of Highly Efficient Electrooptic Stilbazolium Crystals by Sequential Crystal Growth in Different Solvents

作者：Kim Pil Joo; Jazbinsek Mojca; Kwont O Pil^*

来源：Crystal Growth & Design, 2011, 11(7): 3060-3064.

DOI：10.1021/cg200329m

We report on selective growth of highly efficient nonlinear optical stilbazolium crystals by using sequential crystal growth in different solvent systems. Stilbazolium-salt crystals DSTMS (N,N-dimethylamino-N'-methylstilbazolium 2,4,6-trimethylbenzenesulfonate) with state-of-the-art nonlinear optical properties exhibit a thin plate like morphology when grown in methanol and a thick trapezoidal-like morphology when grown in acetonitrile. We demonstrate morphology and thickness control of bulk DSTMS crystals by using sequential crystal growth by choosing a different solvent for growing bulk crystals as for growing seed crystals. For crystals growing in methanol solution from trapezoidal-like seed crystals grown in acetonitrile solution, the average growth rate is similar as in methanol alone, but the specific growth rate is considerably different: the aspect ratio of such crystals may be 1 order of magnitude larger than for crystals growing in methanol alone. For crystals growing in acetonitrile solution from thin plate-like seed crystals grown in methanol solution, the thickness slowly increases, while the lateral size remains similar. Such morphology and thickness control of DSTMS by sequential crystal growth in different solvents is a promising technique for practical applications, where crystals of a certain thickness are desired, for example, for THz-wave generation, frequency conversion, electro-optics, and field detection.

• 出版日期2011-7