A small tris(imidazolium) cage forms an N-heterocyclic carbene complex with silver(I)

作者:Willans Charlotte E; Anderson Kirsty M; Junk Peter C; Barbour Leonard J; Steed Jonathan W*
来源:Chemical communications, 2007, (35): 3634-3636.
DOI:10.1039/b708692j

摘要

A small, sterically rigid tris(imidazolium) cyclophane reacts with Ag2O to give an Ag(I) carbene complex in which one of the imidazolium moieties remains protonated.

  • 出版日期2007