Dynamic Softening or Stiffening a Supramolecular Hydrogel by Ultraviolet or Near-Infrared Light

作者:Zheng, Zhao; Hu, Jingjing; Wang, Hui; Huang, Junlin; Yu, Yihua; Zhang, Qiang; Cheng, Yiyun*
来源:ACS Applied Materials & Interfaces, 2017, 9(29): 24511-24517.
DOI:10.1021/acsami.7b07204

摘要

The development of light-responsive hydrogels that exhibit switchable size and mechanical properties with temporal and spatial resolution is of great importance in many fields. However, it remains challenging to prepare smart hydrogels that dramatically change their properties in response to both ultraviolet (UV) and near-infrared (NIR) lights. Here, we designed a dual-light responsive supramolecular gel by integrating UV light-switchable host guest recognition, temperature responsiveness, and NIR photothernial ability in the gel. The gel could rapidly self-heal and is capable of both softening and stiffening controlled by UV and NIR lights, respectively. Besides stiffness modulation; the bending direction of the gel can be controlled by DV or NIR light irradiation. The smart gel makes it possible to generate dynamic materials that respond to both UV and NIR lights and represents a useful tool that might be used to modulate cellular microenvironments with spatioternporal resolution.