A novel two-fold interpenetrating 3D 4(2)center dot 8(4) network self-assembled from a new 1D coordination polymer

作者：Lu JY^*; Fernandez WA; Ge ZH; Abboud KA

来源：New Journal of Chemistry, 2005, 29(3): 434-438.

DOI：10.1039/b412334d

A new metastable coordination polymer, [Cu(4,4'-bipy)(NO3)(2)](n) (4,4'-bipy = 4,4'-bipyridine, 1), has been synthesized. Its subsequent reactions with additional 4,40-bipy resulted in a self-assembled metal-organic framework, {[Cu(4,4'-bipy)(2)(H2O)(2)][Cu(4,4'-bipy)(2)(H2O)(NO3)]}(NO3)(3).12H(2)O (2), featuring two-fold interpenetrating 3D 4(2).8(4) networks.

• 出版日期2005