Study on the optical polarized properties for the PbWO4 crystal with a pair of V-Pb(2-)-V-O(2+)

作者：Liu TY^*; Zhang QR; Zhuang SL

来源：Journal of Electron Spectroscopy and Related Phenomena, 2005, 142(2): 139-143.

DOI：10.1016/j.elspec.2004.10.009

• PbWO4
• electronic structure
• optical properties
• a pair of V-Pb(2-)-V-O(2+)

The electronic structures, dielectric function, complex refractive index and absorption spectra of both the perfect PbWO4 Crystal and the crystal containing a pair of V-Pb(2-) -V-O(2+) have been calculated using LAPW + lo method with the lattice structure optimized. The results indicate that the optical properties of the PWO crystal exhibit anisotropy and its optical symmetry coincides with lattice structure geometry of the PWO crystal. The absorption spectrum of the PWO crystal containing a pair of V-Pb(2+)-V-O(2+) also does not occur in the visible and near-ultraviolet range. It reveals that the existence of the pair of V-Pb(2+)-V-O(2+) in PWO crystal has no visible effects on the optical properties of the PWO crystal.

• 出版日期2005-2
• 单位上海大学