Analytical Investigations of Spin-Spin, Spin-Other-Orbit and Combined Mechanisms of Zero-Field Splitting for 3d(3) Ions at Trigonal Symmetry

作者：Wei Qun^*

来源：Zeitschrift fur Naturforschung Section A-A Journal of Physical Sciences, 2009, 64(9-10): 646-652.

DOI：10.1515/zna-2009-9-1017

• 3d(3) Ions
• Approximate Analytical Expression
• Complete Diagonalization Method
• Magnetic Interactions Mechanisms

A new method of obtaining approximate analytical expressions of zero-field splitting (ZFS) has been proposed. By analyzing the magnetic interaction mechanisms which affect the properties of ZFS of ground (4)A(2) state for 3d(3) ions at trigonal symmetry, and comparing with the calculated results of complete diagonalization method, the approximate analytical expressions of the contribution to zero-field splitting of (4)A(2) state from spin-spin (SS), spin-other-orbit (SOO), and combined mechanisms have been obtained. Also the applicability of these approximate analytical expressions has been analyzed. It is shown that the approximate analytical expressions are suitable in a wide crystal field parameters range.

• 出版日期2009-10
• 单位宝鸡文理学院