The supramolecular architecture of the second coordination sphere complex between the ammonia adduct of tris(pentafluorophenyl)borane and pyrimidine: Two interpenetrating chiral (10,3)-a (srs) nets assembled through hydrogen bonding

作者：Fuller Anna Marie; Hughes David L; Kostakis George E^*; Lancaster Simon J; Powell Annie K

来源：Inorganica Chimica Acta, 2011, 366(1): 380-383.

DOI：10.1016/j.ica.2010.10.022

• X-ray crystal structure
• Hydrogen bonding
• Supramolecular chemistry

Treatment of the ammonia adduct of tris(pentafluorophenyl)borane with 1.5 equivalents of pyrimidine affords a crystalline supramolecular complex. The solid state structure of the chloroform solvate has been determined by X-ray crystallography and is composed of two interpenetrating chiral (10,3)-a (srs) nets assembled through N-H center dot center dot center dot N hydrogen bonding interactions.

• 出版日期2011-1-30