Alternating Ring-Opening Copolymerization of Cyclohexene Oxide with Phthalic Anhydride Catalyzed by Iron(III) Salen Complexes

作者：Mundil Robert; Host'alek Zdenek; Sedenkova Ivana; Merna Jan^*

来源：Macromolecular Research, 2015, 23(2): 161-166.

DOI：10.1007/s13233-015-3022-4

• polyesters
• iron salen complexes
• catalysis
• anhydride epoxide copolymerization

A series of three iron(III) salen complexes was synthesized and successfully used for copolymerization of cyclohexene oxide and phthalic anhydride. Catalytic systems based on an iron(III) salen complex in combination with 4-(dimethylamino) pyridine (DMAP) or bis(triphenylphosphine) iminium chloride (PPNCl) cocatalysts produced purely alternating copolymer with narrow molar mass distributions. [N, N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexylenediamine] iron(III) chloride was the most active complex and afforded the copolymer even in the absence of the cocatalysts. Other iron complexes were completely inactive in absence of a cocatalyst. Both DMAP and PPNCl alone were able to catalyze the copolymerization, affording purely alternating copolymers in good yields.

• 出版日期2015-2