摘要

The microstructure and electrochemical properties of hybrids, combining single-walled carbon nanotubes (SWCNTs) and DNA, were investigated. TEM images of the SWCNT-DNA hybrids show that most bundled SWCNTs in the starting materials are isolated into individual ones during the sonication-promoted self-assembly. AFM observation further indicates that the sidewalls of SWCNTs are helically wrapped by DNA, which results in stable SWCNT-DNA complexes. The catalyst particles are totally removed during this self-assembly process, thus the SWCNTs are also purified. The electrochemical properties of the SWCNTs are substantially improved due to the hybridization of DNA and the specific capacitance of the SWCNT-DNA hybrids is increased by of 117.9% compared to the parent SWCNTs.

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