科研之友
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摘要
In this study, a selective heating technique by irradiating an infrared laser to an immiscible polymer blend was proposed to actively control the distribution of the dispersed phase in the blend. In the technique, the viscosity ratio between the matrix and dispersed phases was not changed by the molecular weight or shear rate but was changed by the controlled temperature distribution due to selective heating. The feasibility of the proposed technique was investigated through a numerical simulation of the temperature field and an experimental study using a test blend. The results showed that the technique successfully caused the deformation of relatively large droplets and enhanced the micro-scale dispersion. It was also confirmed that the droplet size of the dispersed phase could be estimated by a simple method similar to the conventional technique: the chart of capillary number change with respect to the viscosity ratio. From the obtained results, it was concluded that the technique proposed in this study is a promising candidate for the development of a new blend process.
- 出版日期2013-9-15
