Asymmetric Construction of a Ferrocenyl Phosphapalladacycle from Achiral Enones and a Demonstration of Its Catalytic Potential

作者：Gan Kennard; Sadeer Abdul; Xu Chang; Li Yongxin; Pullarkat Sumod A^*

来源：Organometallics, 2014, 33(19): 5074-5076.

DOI：10.1021/om5007215

A new approach toward ferrocenyl phosphapalladacycle construction from achiral enones via asymmetric hydrophosphination and subsequent diastereoselective CH activation is described. Its catalytic efficacy toward CC bond formation is subsequently illustrated.

• 出版日期2014-10-13
• 单位南阳理工学院