Application of multi-functional chestnut shell in one-step preparing Fe3O4@C magnetic nanocomposite with high adsorption performance

作者：Zhang, Lina; Han, Yuqi; Yang, Zhiwang; Su, Bitao^*

来源：Fullerenes, Nanotubes, and Carbon Nanostructures, 2018, 26(8): 471-478.

DOI：10.1080/1536383X.2018.1448792

• Fe3O4@C nanocomposite
• chestnut shell
• one-step hydrothermal method
• magnetism
• adsorptive property

Chestnut shell (CS) acts as a multi-functional material in the one-step preparation of Fe3O4@C nanocomposite via hydrothermal method by using Fe(NO3)(3) as Fe source without adding any other additives. The characterized results show that under required hydrothermal conditions, a proper amount of CS can reduce a certain amount of adsorbed/enriched Fe3+ to Fe2+ to ensure the 2:1 molar ration of Fe3+ to Fe2+ and the in-situ formation of goal phase Fe3O4 on the surface of the CS. Meanwhile, CS is carbonized to C material similar to graphene oxide. In the preparation process of the composite of Fe3O4@C, CS plays multiple roles, such as promoter, reductive agent, C-source, and template, to endow a certain morphology of the nanocomposite Fe3O4@C. The composite material shows good magnetic separability and adsorption property for methylene blue (MB) solution. Furthermore, the adsorptive kinetic behavior of the Fe3O4@C is investigated. The method is simple, fast, low cost and green and really realizes the full use of wasteful resource CS.

• 出版日期2018
• 单位西北师范大学