A non-linear optical crystal, Cd3Zn3(BO3)(4)

作者：Sun TQ^*; Pan F; Wang RJ; Shen GQ; Wang XQ; Shen DZ

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2003, 59: I107-I108.

DOI：10.1107/S0108270103020390

The title compound, tricadmium trizinc tetraborate, Cd3Zn3(BO3)(4), is a new non-linear optical (NLO) crystal and its structure has been determined by single-crystal X-ray diffraction. This compound is composed of planar [BO3](3-) groups sharing O atoms with CdO4 or ZnO4 tetrahedra. The BO3 triangles are located on threefold axes and are arranged with nearly the same orientation. The Cd and Zn atoms are disordered on the same site in the proportion 1:1. A strong second harmonic generation of Nd:YAG laser radiation (lambda = 1064 nm) has been observed for a crystal of the title compound.

• 出版日期2003-11
• 单位清华大学