科研之友
微信
新浪微博
Facebook
分享链接
摘要
The effects of a spin-orbit interaction on transition-metal ions of (4d)(3)- and (5d)(3)-based oxides in which three electrons occupy t(2g) orbitals are studied. The amplitude of the magnetic moment of d electrons on the 5d and 4d orbitals is estimated by numerical diagonalization. It is found that the magnetic moment is reduced by the spin-orbit interaction. It is suggested that (4d)(3)- and (5d)(3)-based oxides are located in the middle of the L-S and J-J coupling schemes.
- 出版日期2013-7
