Lanthanide based coordination polymers chill, relax under magnetic field and also fluoresce

作者:Goswami Soumyabrata; Adhikary Amit; Jena Himanshu Sekhar; Konar Sanjit*
来源:Dalton Transactions, 2013, 42(27): 9813-9817.
DOI:10.1039/c3dt51195b

摘要

Three lanthanide one-dimensional coordination polymers, obtained using Ln(3+) salts and croconate dianion, were structurally characterized. Magnetic studies reveal that the gadolinium analogue exhibits a large magnetocaloric effect while single-molecule magnet behaviour is observed in the dysprosium analogue.

  • 出版日期2013