Microwave Specific Specific Effect on Catalytic atropo-Enantioselective Ring-Opening Reaction of Biaryl Lactones

作者:Tashima Shigeki; Nushiro Kazuya; Saito Kodai; Yamada Tohru*
来源:Bulletin of the Chemical Society of Japan, 2016, 89(7): 833-835.
DOI:10.1246/bcsj.20160104

摘要

The microwave specific effect on the catalytic atropo-enantioselective ring-opening reaction of biaryl lactones was investigated. Under strictly controlled temperature conditions, the reaction was accelerated by microwave irradiation without any loss of the enantioselectivity. Also, the racemization rate of the atropo-optically active biaryl lactone was enhanced by the microwave irradiation.

  • 出版日期2016-7-15