A fishing rod-like conjugated polymer bearing pillar[5]arenes

作者:Ma, Yingjie; Chen, Long; Li, Chen; Mullen, Klaus*
来源:Chemical communications, 2016, 52(40): 6662-6664.
DOI:10.1039/c6cc02059c

摘要

A novel diethynyl functionalized pillar[5]arene, that is a pentabenzen-acyclodecaphane derivative, has been synthesized and polymerized with p-dihalobenzene to form a fishing rod-like conjugated polymer, where one of the benzenes in the pillar[5]arene rings is incorporated into a poly(arylene ethynylene) backbone.