Nano-rod catalysts: Building MOF bottles (MIL-101 family as heterogeneous single-site catalysts) around vanadium oxide ships

作者：Fazaeli Razieh^*; Aliyan Hamid; Moghadam Majid; Masoudinia Mona

来源：Journal of Molecular Catalysis A: Chemical , 2013, 374: 46-52.

DOI：10.1016/j.molcata.2013.03.020

• Supported vanadia catalyst
• Impregnation method
• Single-site catalysts (SSC)
• MOF bottles (MIL-101(Cr))

Porous materials based on chromium (III) terephthalate metal organic frameworks (Cr-MIL(101)) and their new composites with vanadium oxide has emerged as a potential catalyst because of its high specific surface area, tunable pore size, and unique structure. The structural and textural characterization of V@MIL(101) were done using FTIR, X-ray diffraction, N-2 adsorption-desorption, and TEM. XRD and adsorption-desorption analysis shows that the mesostructure of MIL-101 remains intact after vanadium oxide modifications, while spectral technique show the successful immobilizing of the neat vanadium oxide inside the MIL-101 cavities. These new catalysts were found to be highly effective for selective oxidation of sulfides to sulfoxides and sulfones with H2O2 at room temperature and the 4.2% V@MIL(101) catalyst showed the highest activity. The PW12@MCFim heterogeneous system showed high catalytic oxidative activity in the treatment of commodity gasoline.

• 出版日期2013-8