摘要

Methyl abstraction from a neutral aluminum complex stabilized by a salen-like fluorinated dialkoxide-diimino ligand yields the corresponding cationic species, which exists as alive-coordinate Et(2)O adduct in the solid state and in solution. This complex promotes the cationic polymerization of propylene oxide and p-methylstyrene at low temperatures.

  • 出版日期2010-4-12