An oxidative cyclopropanation reaction of primary nitro compounds using Fe2O3

作者：Moriyama Takaaki; Ito Yuji; Koyama Yusuke; Kawamoto Takuji; Kamimura Akio

来源：Tetrahedron Letters, 2016, 57(29): 3127-+.

DOI：10.1016/j.tetlet.2016.06.013

• Cyclopropanes
• Nitro compounds
• Ferric oxide
• Intramolecular cyclopropanation

Alkenylnitro compounds underwent oxidative cyclopropanation by treatment with Fe2O3 in the presence of base and iodine. Bicyclic nitrocyclopropanes were readily prepared in a highly stereoselective manner.

• 出版日期2016-7-20