Seaweed-Derived Route to Fe2O3 Hollow Nanoparticles/N-Doped Graphene Aerogels with High Lithium Ion Storage Performance

作者：Liu, Long; Yang, Xianfeng; Lv, Chunxiao; Zhu, Aimei; Zhu, Xiaoyi; Guo, Shaojun^*; Chen, Chengmeng; Yang, Dongjiang^*

来源：ACS Applied Materials & Interfaces, 2016, 8(11): 7047-7053.

DOI：10.1021/acsami.5b12427

• seaweed
• egg box
• Kirkendall effect
• hollow nanoparticles
• lithium ion batteries

We developed a nanoscale Kirkendall effect assisted method for simple and scalable synthesis of three-dimensional (3D) Fe2O3 hollow nano particles (NPs)/graphene aerogel through the use of waste seaweed biomass as new precursors. The Fe2O3 hollow nanoparticles with an average shell thickness of similar to 6 nm are distributed on 3D graphene aerogel, and also act as spacers to make the separation of the neighboring graphene nanosheets. The graphene Fe2O3, aerogels exhibit high rate capability (550 mA h g(-1) at S A g(-1)) and excellent cyclic stability (729 mA h g(-1) at 0.1 A g(-1) for 300 cycles), outperforming all of the reported. Fe2O3/graphene hybrid electrodes, due to the hollow structure of the active Fe2O3 NPs and the unique structure of the 3D graphene aerogel framework. The present work represents an important step toward high,level control of high-performance 3D graphene Fe-based NPs aerogels for maximizing lithium storage with new horizons for important fundamental and technological applications.

• 出版日期2016-3-23
• 单位北京大学; 中国科学院山西煤炭化学研究所; 青岛大学; 华南理工大学