Acid-Base Control of Valency within Carboranedithiol Self-Assembled Monolayers: Molecules Do the Can-Can

作者：Thomas John C; Goronzy Dominic P; Serino Andrew C; Auluck Harsharn S; Irving Olivia R; Jimenez Izal Elisa; Deirmenjian Jacqueline M; Machacek Jan; Sautet Philippe; Alexandrova Anastassia N; Base Tomas; Weiss Paul S

来源：ACS Nano, 2018, 12(3): 2211-2221.

DOI：10.1021/acsnano.7b09011

• Carborane
• Dipoles
• Molecular switch
• Nanoscience
• Scanning tunneling microscopy
• Self-assembled monolayer
• Self-assembly
• Two-dimensional

We use simple acid-base chemistry to control the valency in self-assembled monolayers of two different carboranedithiol isomers on Au{111}. Monolayer formation proceeds via Au-S bonding, where manipulation of pH prior to or during deposition enables the assembly of dithiolate species, monothiol/mono...

• 出版日期2018-3