A novel chemiluminescence system with diperiodatonickelate (IV) for the determination of adrenaline

作者：Yang, Chunyan^*; Chen, Fubin; Chang, Ziqiang; Sun, Yonghua; Zhang, Zhujun

来源：Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2014, 121: 288-291.

DOI：10.1016/j.saa.2013.10.094

• Chemiluminescence
• Diperiodatonickelate
• Adrenaline

A novel chemiluminescence (CL) system with diperiodatonickelate (IV) (DPN) was developed for the determination of adrenaline for the first time. The possible CL emission mechanism was briefly discussed by comparing the fluorescence emission spectra with CL spectra. Under the optimum conditions, the relative CL intensity was linear over the concentration of AD ranging from 1.0 x 10(-7) to 1.0 x 10(-5) g mL(-1) with a detection limit of 4.0 x 10(-8) g mL(-1) (3 sigma). And the relative standard deviation was 3.7% for 2.0 x 10(-6) g mL(-1) AD (n = 11). The developed method has been successfully applied to the determination of AD in pharmaceutical preparations.

• 出版日期2014-3-5
• 单位西华师范大学; 陕西师范大学; 成都理工大学