A new synthetic approach to functionalize oxomolybdenum complexes

作者:Chen Baokuan*; Lin Zhengguo; Wang Bo; Feng Xiao; Fan Linyuan; Yang Song; Huang Xianqiang; Hu Changwen
来源:CrystEngComm, 2013, 15(37): 7410-7413.
DOI:10.1039/c3ce40994e

摘要

A new synthetic approach is developed and nine distinct organic functionalized oxomolybdenum complexes, 1-9, are synthesized and fully characterized. Specifically by altering the functional groups on imidazoles we succeeded in making a series of crystalline structures with unique underlying topologies and/or functionalities. These imidazole derivatives can act as ligands, structural directing agents, counter cations and simultaneously, solvents where the reactions and the crystallization occur.