Post-modified acid-base bifunctional MIL-101(Cr) for one-pot deacetalization-Knoevenagel reaction

作者：Mu, Manman; Yan, Xilong; Li, Yang; Chen, Ligong^*

来源：Journal of Nanoparticle Research, 2017, 19(4): 148.

DOI：10.1007/s11051-017-3844-4

• Bifunctional MIL-101
• Post-synthetic
• Deacetalization-Knoevenagel reaction
• Synergistic effect
• Nanocrystals
• Nanostructures

A novel and convenient approach for the construction of the bifunctional MIL-101 material bearing sulfonic acid and amino groups was established via the post-synthetic modification. This material possesses high BET surface area (1446 m(2)/g) and large pore volume (0.77 cm(3)/g). Significantly, this material could serve as a bifunctional heterogeneous catalyst and was initially employed for one-pot deacetalizationKnoevenagel reaction, exhibiting excellent catalytic performance (yield 99.74%). More importantly, it can be easily recovered and reused at least three times. Finally, our proposed catalytic mechanismindicated that amino and the sulfonic acid groups played a synergistic effect on this one-pot deacetalization-Knoevenagel reaction.

• 出版日期2017-4-17
• 单位天津大学