A heteropentanuclear oxalato-bridged [(Re4GdIII)-Gd-IV] complex: synthesis, crystal structure and magnetic properties

作者:Martinez Lillo Jose*; Canadillas Delgado Laura; Cano Joan; Lloret Francesc; Julve Miguel; Faus Juan
来源:Chemical Communications, 2012, 48(74): 9242-9244.
DOI:10.1039/c2cc33350c

摘要

The compound (NBu4)5[Gd-III{(ReBr4)-Br-IV(mu-ox)}(4)(H2O)]center dot H2O(1), with intramolecular antiferromagnetic coupling, is the first Re(IV) system incorporating a 4f ion.

  • 出版日期2012