Iterative Synthesis of Heterotelechelic Oligo(phenylene-vinylene)s by Olefin Cross-Metathesis

作者：Norris Benjamin N; Pan Tianqi; Meyer Tara Y^*

来源：Organic Letters, 2010, 12(23): 5514-5517.

DOI：10.1021/ol102398y

A novel iterative synthesis of heterotelechelic oligo(phenylene-vinylene)s using olefin cross-metathesis is reported. The metathesis homologation proceeds in good yields and allows for further functionalization, including the facile formation of donor-acceptor complexes and repeating sequence copolymers.

• 出版日期2010-12-3