Hydrothermal Synthesis, Crystal Structure and Luminescence Property of a 1D Chain Coordination Polymer {[Cd-2(1,8-nap)(2)(H2O)(2)](bpp)(2)}(n)

作者：Feng Xia; Tang Zhi Wei; Feng Yun Long; Lan You Zhao; Wen Yi Hang^*

来源：Chinese Journal of Inorganic Chemistry, 2008, 24(10): 1713-1717.

• cadimum(II) complex
• crystal structure
• luminescence property

The title complex {[Cd-2(1,8-nap)(2)(H2O)(2)](bpp)(2)}(n) (1), a cadmium complex based on mixed napthalene-1,8-dicarboxylate (1,8-nap) and flexible 1,3-bi(4-pyridyl)propane (bpp) ligands, has been hydrothermally synthesized. It consists of a one-dimensional chain along c axis, which is derived from dimeric unit [Cd-2 (1,8-nap)(2)(H2O)(2)] linked by a pair of bpp ligands. In every [Cd-2(1,8-nap)(2)(H2O)(2)] dimeric unit, two 1,8-nap act as bridging ligands to connect two Cd(II) atoms, forming a sixteen-membered ring. Each Cd(II) atom is in a distorted octahedral environment, coordinated by one aqua, two 1-8-nap and two bridging bpp ligands. In addition, two bridging bpp ligands connected two neighboring Cd(II) atoms form a twenty-four-membered ring. The TGA and Luminescence property in solid state of complex 1 have been further studied and discussed in this paper. CCDC: 669293.

• 出版日期2008-10
• 单位浙江师范大学