Decomposition of pentaammineaquacobalt(III) perchlorate under laser radiation action

作者：Abdrashitov G O; Aver'yanov A O; Bal'makov M D; Ilyushin M A; Tverjanovich A S^*; Tver'yanovich Yu S

来源：Russian Journal of General Chemistry, 2017, 87(7): 1451-1455.

DOI：10.1134/S1070363217070015

• energy-saturated cobalt complexes
• laser-induced decomposition of complexes

Photolytic decomposition of the complex [Co(NH3)(5)(H2O)](ClO4)(3) under the action of a laser with a wavelength of 355 nm, which is resonant in energy to the energy of the ((1) A (1g) -> (1) T (2g) ) d-d transition, was studied. Decomposition of the complex is accompanied by a release of ammonia with its subsequent oxidation to nitrogen oxides and by partial cobalt reduction with the formation of the mixed cobalt(II, III) oxide Co3O4.

• 出版日期2017-7