Microscopic origin of magnetism and magnetic interactions in ferropnictides

作者：Johannes M D^*; Mazin I I

来源：Physical Review B, 2009, 79(22): 220510.

DOI：10.1103/PhysRevB.79.220510

• barium compounds
• Fermi surface
• iron compounds
• magnetic moments
• metal-insulator transition
• spin-Peierls transition
• superexchange interactions

One year after their initial discovery, two schools of thought have crystallized regarding the electronic structure and magnetic properties of ferropnictide systems. One postulates that these are itinerant weakly correlated metallic systems that become magnetic by virtue of spin-Peierls-type transition due to near nesting between the hole and the electron Fermi-surface pockets. The other argues that these materials are strongly or at least moderately correlated and the electrons are considerably localized and close to a Mott-Hubbard transition, with the local magnetic moments interacting via short-range superexchange. In this Rapid Communication we argue that neither picture is fully correct. The systems are moderately correlated but with correlations driven by Hund's rule coupling rather than by the on-site Hubbard repulsion. The iron moments are largely local, driven by Hund's intra-atomic exchange. Superexchange is not operative, and the interactions between the Fe moments are considerably long range and driven mostly by one-electron energies of all occupied states.

• 出版日期2009-6