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摘要
The first nickel-catalyzed C-H selective fluorination of 8-aminoquinoline derivatives at the C-5 position was achieved using NFSI (N-fluorobenzenesulfonimide) as the "F" source and NiSO4 as the catalyst. This method demonstrated broad substrate tolerance under mild conditions and a plausible SET (single electron transfer) mechanism was suggested in the proposal of a radical process.
- 出版日期2017-8-1
- 单位吉林大学
