Application of the Nernst-Planck approach to lead ion exchange in Ca-loaded Pelvetia canaliculata

作者：Costa Joana F de Sa S; Vilar Vitor J P^*; Botelho Cidalia M S; da Silva Eduardo A B; Boaventura Rui A R

来源：Water Research, 2010, 44(13): 3946-3958.

DOI：10.1016/j.watres.2010.04.033

• Ion exchange
• Nernst-Planck equations
• Biosorption
• Pelvetia canaliculata
• Lead ions

Ca-loaded Pelvetia canaliculata biomass was used to remove Pb(2+) in aqueous solution from batch and continuous systems. The physicochemical characterization of algae Pelvetia particles by potentiometric titration and FTIR analysis has shown a gel structure with two major binding groups - carboxylic (2.8 mmol g(-1)) and hydroxyl (0.8 mmol g(-1)), with an affinity constant distribution for hydrogen ions well described by a Quasi-Gaussian distribution. Equilibrium adsorption (pH 3 and 5) and desorption (eluents: HNO(3) and CaCl(2)) experiments were performed, showing that the biosorption mechanism was attributed to ion exchange among calcium, lead and hydrogen ions with stoichiometry 1:1 (Ca:Pb) and 1:2 (Ca:H and Pb:H). The uptake capacity of lead ions decreased with pH, suggesting that there is a competition between H(+) and Pb(2+) for the same binding sites. A mass action law for the ternary mixture was able to predict the equilibrium data, with the selectivity constants alpha(H)(Ca) = 9 +/- 1 and alpha(Pb)(Ca) = 44 +/- 5, revealing a higher affinity of the biomass towards lead ions. Adsorption (initial solution pH 4.5 and 2.5) and desorption (0.3 M HNO(3)) kinetics were performed in batch and continuous systems. A mass transfer model using the Nernst-Planck approximation for the ionic flux of each counter-ion was used for the prediction of the ions profiles in batch systems and packed bed columns. The intraparticle effective diffusion constants were determined as 3.73 x 10(-7) cm(2) s(-1) for H(+), 7.56 x 10(-8) cm(2) s(-1) for Pb(2+) and 6.37 x 10(-8) cm(2) s(-1) for Ca(2+).

• 出版日期2010-7