Deformation and Fracture Behavior of Metallic Glassy Alloys and Glassy-Crystal Composites

作者：Louzguine Luzgin D V^*; Vinogradov A; Li S; Kawashima A; Xie G; Yavari A R; Inoue A

来源：Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science, 2011, 42A(6): 1504-1510.

DOI：10.1007/s11661-010-0391-3

The present work demonstrates the deformation behavior of Zr-Cu-Ni-Al bulk glassy alloys and Zr-Ni-Cu-Al-Pd glassy foils as well as Ni-Cu-Ti-Zr bulk crystal-glassy composites. Fracture of Zr(60)Cu(16)Ni(14)Al(10) and Zr(64.13)Ni(10.12)Cu(15.75)Al(10) bulk glassy alloys is featured by nearly equal fraction areas of cleavage-like and vein-type relief. The observed pattern of alternating cleavage-like and vein-type patterns illustrates a result of dynamically self-organizing shear propagation at the final catastrophic stage. The deformation behavior of Zr(64.13)Ni(10.12)Cu(15.75)Al(10) alloy has also been tested at LN(2) temperature. The strength of the sample decreases with temperature, and no clear serrated flow typical for bulk glassy samples tested at room temperature is observed in the case of the samples tested at LN(2) temperature. We also studied the deformation behavior of Zr-Ni-Cu-Al-Pd glassy foils thinned to electron transparency in situ in tension in a transmission electron microscope. We also present a Ni-Cu-Ti-Zr crystal-glassy composite material having a superior strength paired with a considerable ductility exceeding 10 pct. The metastable cP2 crystalline phase promotes a strain-induced martensitic transformation leading to pseudoelastic behavior as well as enhanced plasticity at room temperature. Underlying mechanisms of plastic deformation are discussed in terms of the interplay between the dislocation slip in the crystalline phase and the shear deformation in the glassy matrix.

• 出版日期2011-6