Doebner condensation in ionic liquids [Bmim]BF4 and [Bpy]BF4 to synthesize alpha, beta-unsaturated carboxylic acid

作者：Jiang Dong; Wang Yuan Yuan; Xu Yan Nan; Dai Li Yi^*

来源：Chinese Chemical Letters, 2009, 20(3): 279-282.

DOI：10.1016/j.cclet.2008.12.005

• Ionic liquid
• Doebner condensation
• alpha, beta-Unsaturated carboxylic acid
• Decarboxylation

Ionic liquids [Bmim]BF4 and [Bpy]BF4 were employed as environmentally benign media in Doebner condensation to synthesize a, P-unsaturated carboxylic acid. The good results showed that [Bmim]BF4 and [Bpy]BF4 were efficient media for Doebner condensation, which could be recycled easily. The highest yields could reach 93% and 90% in [Bmim]BF4 and [Bpy]BF4, respectively.

• 出版日期2009-3
• 单位华东师范大学