A study of microporous aluminophosphates obtained in the presence of symmetrical di-n-alkylamines

作者：Kikhtyanin O V^*; Toktarev A V; Ayupov A B; Boldyreva N N; Echevskii G V

来源：Russian Chemical Bulletin, 2012, 61(10): 1867-1876.

• microporous aluminophosphates
• ATO structural type
• hydrothermal synthesis
• di-n-alkylamines
• di-n-propylamine
• di-n-butylamine
• di-n-pentylamine
• di-n-hexylamine

Microporous aluminophosphates and silicoaluminophosphates were obtained by hydrothermal synthesis with a number of symmetrical di-n-alkylamines as templates. The influence of the reagents and chemical composition of the starting reaction gel on the phase composition of the products obtained was studied. Pure ATO-type crystals were formed when the organic component was abundant in the reaction mixture and aluminum isopropoxide served as an aluminum source. Various physicochemical investigations revealed that the properties of the products obtained depend on the amine nature.

• 出版日期2012-10