A trimetallic compound containing Zn-Zr bonds: Cp2Zr(ZnR)(2) (Cp = C5H5; r = C6H3-2,6-(2,4,6-i-Pr3C6H2)(2))

作者：Wang Yuzhong; Quillian Brandon; Wannere Chaitanya S; Wei Pingrong; Schleyer Paul v^*; Robinson Gregory H

来源：Organometallics, 2007, 26(12): 3054-3056.

DOI：10.1021/om700319k

m-Terphenylzinc iodides RZnI2Li(OEt2)(2) (1) and RZnI (2) (R = C6H3-2,6-(2,4,6-i-Pr3C6H2)(2)) were prepared and structurally characterized. The sodium metal reduction of Cp2ZrCl2 with 2 afforded Cp2Zr(ZnR)(2) (3) as the first structurally characterized compound containing a Zn-Zr bond. The nature of the unique Zn-Zr bond for 3 was further probed by DFT computations.

• 出版日期2007-6-4