An azido-Cu-II-triazolate complex with utp-type topological network, showing spin-canted antiferromagnetism

作者:Li Jian Rong; Yu Qun; Carolina Sanudo E; Tao Ying; Bu Xian He*
来源:Chemical communications, 2007, (25): 2602-2604.
DOI:10.1039/b702988h

摘要

An azido-metal-1,2,4-triazolate coordination polymer, [Cu(trz)(N-3)](n) (trz = 1,2,4-triazolate) was synthesized using hydrothermal methods; the complex has a rare three-dimensional non-interpenetrated utp or (10,3)-d topological network structure and exhibits spin-canted antiferromagnetism at low temperature.