科研之友
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摘要
Rhodium-catalyzed highly regio-and enantioselective hydroamination of allenes is reported. Exclusive branched selectivities and excellent enantioselectivities were achieved applying a rhodium(I)/Josiphos catalyst. This method permits the practical synthesis of valuable alpha-chiral allylic amines using benzophenone imine as ammonia carrier.
- 出版日期2016
