Limits of the Classical Concept of Concentration

作者:Maioli Marco; Varadi Gyula; Kurdi Robert; Caglioti Luciano; Palyi Gyula*
来源:Journal of Physical Chemistry B, 2016, 120(30): 7438-7445.
DOI:10.1021/acs.jpcb.6b02904

摘要

Solutions of very low concentrations cannot be treated by the usual concept of concentration. Stochastic calculations are performed for the analysis of such solutions containing one or a few molecule(s). It is concluded that these systems escape the usual concentration parameters. Two "case histories" are also shown for demonstration of the practical consequences of the theoretical analysis.

  • 出版日期2016-8-4