Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(III) phosphoramidate complex

作者：Drover Marcus W; Schafer Laurel L^*; Love Jennifer A^*

来源：Dalton Transactions, 2017, 46(26): 8621-8625.

DOI：10.1039/c7dt01499f

The reaction of a Cp*Ir(III) phosphoramidate complex with secondary amines gives amine, imine-bound Cp*Ir(III) hydride complexes resulting from amine dehydrogenation. These well-characterized species could serve as models of relevant intermediates that have been proposed in catalytic amine dehydrogenation using related N, O-chelated Cp*Ir(III) pyridonate complexes.

• 出版日期2017-7-14