Divergent reactivity of nitric oxide with metal-metal quintuple bonds

作者：Wu Pei Fang; Liu Shih Cheng; Shieh Yun Jen; Kuo Ting Shen; Lee Gene Hsiang; Wang Yu; Tsai Yi Chou^*

来源：Chemical Communications, 2013, 49(39): 4391-4393.

DOI：10.1039/c3cc37118b

Reactions of NO with the quintuple bonded chromium and molybdenum amidinate dimers, respectively, gave dichromium nitrosyl nitrito amidinato complexes, and the quadruple bonded dimolybdenum nitrito amidinato species with a paddlewheel configuration.

• 出版日期2013
• 单位清华大学