Glass transition dynamics and conductivity scaling in ionic deep eutectic solvents: The case of (acetamide plus lithium nitrate/sodium thiocyanate) melts

作者：Tripathy Satya N^*; Wojnarowska Zaneta; Knapik Justyna; Shirota Hideaki; Biswas Ranjit; Paluch Marian

来源：Journal of Chemical Physics, 2015, 142(18): 184504.

DOI：10.1063/1.4919946

A detailed investigation on the molecular dynamics of ionic deep eutectic solvents (acetamide + lithium nitrate/sodium thiocyanate) is reported. The study was carried out employing dielectric relaxation spectroscopy covering seven decades in frequency (10(-1)-10(6) Hz) and in a wide temperature range from 373 K down to 173 K, accessing the dynamic observables both in liquid and glassy state. The dielectric response of the ionic system has been presented in the dynamic window of modulus formalism to understand the conductivity relaxation and its possible connection to the origin of localized motion. Two secondary relaxation processes appear below glass transition temperature. Our findings provide suitable interpretation on the nature of secondary Johari-Goldstein process describing the ion translation and orientation of dipoles in a combined approach using Ngai's coupling model. A nearly constant loss feature is witnessed at shorter times/lower temperatures. We also discuss the ac conductivity scaling behavior using Summerfield approach and random free energy barrier model which establish the time-temperature superposition principle. These experimental observations have fundamental importance on theoretical elucidation of the conductivity relaxation and glass transition phenomena in molten ionic conductors.

• 出版日期2015-5-14