A novel 3D CdII-coordination framework with helical units in a mixed flexible ligand system: Encapsulating right-handed helical water chains

作者：Li, Dong-Sheng^*; Zhang, Mei-Li; Zhao, Jun; Wang, Dan-Jun; Zhang, Peng; Wang, Ni; Wang, Yao-Yu

来源：Inorganic Chemistry Communications, 2009, 12(10): 1027-1030.

DOI：10.1016/j.inoche.2009.08.013

• Cd-II-coordination framework
• Helical unit
• Water chain
• Luminescence

In flexible co-ligand system, the P-handed [Cd(bpb)](n) and the M-handed [Cd(pda)](n) helical chains interweave mutually into a novel 3D coordination framework with diamondoid skeleton, namely, {[Cd(1,4-pda)(bpb)(H2O)]center dot H2O}(n) (1) [bpb = 1,4-bi(4-pyridyl)butane, 1,4-H(2)pda = 1,4-phenylenediacetic acid]. Interestingly, I D hydrophilic tunnel of I acts as a template for the formation of the P-handed 1D helical water chains, displaying molecular recognition and chirality transfer. The photoluminescent property and thermal stability of 1 were also discussed.

• 出版日期2009-10
• 单位三峡大学; 延安大学; 西北大学