Direct nucleophilic functionalization of C(sp(2))-H-bonds in arenes and hetarenes by electrochemical methods

作者:Shchepochkin A V*; Chupakhin O N; Charushin V N; Petrosyan V A
来源:Russian Chemical Reviews, 2013, 82(8): 747-771.
DOI:10.1070/RC2013v082n08ABEH004386

摘要

The data on the main electrochemical methods and approaches used for the direct functionalization of the C(sp(2)) - H-bond proceeding via the mechanisms of nucleophilic substitution of hydrogen (S-N(H)-reaction) are classified and summarized. The important features of preparative electrochemical processes are considered. A special emphasis is placed on the synthetic potential of the discussed transformations. The bibliography includes 133 references.

  • 出版日期2013